英国皇家化学会（RSC）是一个拥有超过175年历史的面向全球化学家的非营利会员制机构，旗下拥有43种期刊，其中很多在化学领域有很高影响力。为了进一步帮助广大读者追踪科技前沿热点，X-MOL团队与英国皇家化学会合作，推出英国皇家化学会期刊主编推荐的精彩文章快览，本期文章属“材料领域”，英文点评来自英国皇家化学会期刊的主编。如果大家对我们的解读有更多的补充和点评，欢迎在文末写评论发表您的高见！
Chemical Science （IF: 8.668）
1. GO-guided direct growth of highly oriented metal–organic framework nanosheet membranes for H2/CO2 separation
Chem. Sci., 2018, Advance Article
DOI: 10.1039/C7SC04815G
Researchers in China and Australia report a bottom-up strategy for directly growing a highly oriented Zn2（benzimidazole）4 ZIF nanosheet tubular membrane, based on graphene oxide guided self-conversion of ZnO nanoparticles. The resulting 200 nm thick membrane demonstrated exceptional H2/CO2 gas separation performance, with a H2 performance of 1.4×10-7 mol m-2 s-1 Pa-1 and an ideal separation selectivity of approximately 106. The strategy is particularly suitable for large-scale fabrication of tubular MOF membranes.
大连理工大学和澳大利亚莫纳什大学的研究者们合作报道了一种自下而上的合成策略，基于氧化石墨烯导向的ZnO纳米颗粒自转化，直接生长一种高度取向的锌-苯并咪唑（Zn2（benzimidazole）4）ZIF纳米片管状膜。所合成的200 nm厚的膜表现出了出色的H2/CO2气体分离性能（H2透过率为1.4 × 10-7 mol m-2 s-1 Pa-1）以及理想的分离选择性（约为106）。该方法特别适用于大规模生产制造管状MOF膜。
2. 9,10-Azaboraphenanthrene-containing small molecules and conjugated polymers: synthesis and their application in chemodosimeters for the ratiometric detection of fluoride ions
Chem. Sci., 2018, Advance Article DOI: 10.1039/C8SC00688A
Scientists in China have developed an efficient synthetic procedure for conjugated small molecules and polymers featuring 9,10-azaboraphenanthrene units via aromaticity-driven ring-opening interactions. These molecules and polymers displayed good air and moisture stability, and bright fluorescent properties. The compounds were used as effective and selective ratiometric sensors for fluoride ions in THF solution with 11 anions. The conjugated polymers showed better sensing performance than the molecules due to exciton migration along the conjugated chains.
西安交通大学研究团队发展了一种通过芳香性驱动的开环反应有效合成带有9,10-氮硼杂菲单元的共轭小分子和聚合物的合成方法。这些分子和聚合物展现出了良好的空气和湿度稳定性，并具有明亮的荧光性质。该化合物在含有11种阴离子的THF溶液中，可用作氟离子的高效选择性比率传感器。由于能够沿共轭链进行激子迁移，这种共轭聚合物显示出了比单个分子更好的传感性能。
Polymer Chemistry （IF: 5.375）
1. Cross-linked AIE supramolecular polymer gels with multiple stimuli-responsive behaviours constructed by hierarchical self-assembly
Polym. Chem., 2018, 9, 2021-2030
DOI: 10.1039/C8PY00226F
Here researchers used the principles of hierarchical （step-wise） self-assembly to create stimuli-responsive supramolecular polymer gels. Firstly, the discrete building blocks of the supramolecular structures were synthesised, driven by coordination interactions these self-assembled to create metallacycles. By increasing the concentration of metallacycles and introducing guest molecules the system self-assembled into a crosslinked supramolecular gel. The gels created had aggregation-induced-emission properties and were responsive to stimuli such as temperature and competitive guests.
华东师范大学的研究人员使用分级（逐步）自组装的原理合成了具有刺激响应性的超分子聚合物凝胶。首先，他们合成了构成超分子结构的离散结构单元，并通过配位作用驱动这些结构单元自组装成金属环。之后，通过增加金属环的浓度以及引入客体分子，该体系最终自组装成为交联超分子凝胶。该凝胶具有聚集诱导发光（AIE）性质，并可对温度和竞争性客体分子等刺激产生响应。
2. RAFT polymerization of a RGD peptide-based methacrylamide monomer for cell adhesion
Polym. Chem., 2018, 9, 1780-1786
DOI: 10.1039/C7PY01887H
In this paper a novel RGD peptide-based methacrylamide monomer （MARGD） was synthesised and can be polymerised by RAFT polymerization to afford well-defined polymers （PMARGD） containing a RGD peptide group. In aqueous solutions PMARGD self-assembled into nanoparticles which exhibited pH responsive behaviour, increasing in size as the pH of the solution decreased. Cytotoxicity tests showed biocompatibility.
北京化工大学的研究人员合成了一种新的基于RGD肽的甲基丙烯酰胺单体（MARGD），其可通过直接RAFT聚合反应制备带有RGD肽结构单元的结构确切的聚合物（PMARGD）。在水溶液中，PMARGD会自组装成纳米颗粒，并表现出了pH响应行为，这种纳米颗粒尺寸会随着溶液pH值的下降而增大。细胞毒性测试显示该聚合物具有生物相容性。
Materials Horizons （IF: 10.706）
1. Metal–organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion
Mater. Horiz., 2018, Advance Article
DOI: 10.1039/C8MH00133B
The electrospinning method has provided a new and exciting avenue for fabricating functional 1D hollow carbon materials from MOFs, especially for clean energy utilization. This minireview by Yoshio Bando, Yusuke Yamauchi et al. provides some guidance for future derivations of 1D hollow carbon nanomaterials from MOFs using electrospinning technology.
静电纺丝法为由MOFs材料制造功能性一维（1D）中空碳材料提供了一条令人兴奋的新途径，特别是对清洁能源领域。本篇综述为使用静电纺丝法由MOFs制备一维中空碳纳米材料及其未来发展提供了一些指导。
2. Conducting photopolymers on orthopeadic implants having a switch of priority between promoting osteogenic and antibacterial activity
Mater. Horiz., 2018, Advance Article
DOI: 10.1039/C8MH00285A
For the long-term success of medical implants, the authors of this communication have decorated an implant surface with an intelligent medium based on conducting photopolymers. This surface could switch priority between promoting bone integration and antibacterial activity when a specific electrical stimulus was applied. This opens up new avenues for implants with specific properties needed at different clinical stages of implantation.
为了医疗植入物的长期成效，本文作者将一种基于导电光敏聚合物的智能介质修饰在了植入物表面。当施加特定的电刺激时，该表面可以在促进骨整合和抗菌活性之间切换优先度。该研究为具有不同临床阶段所需特定性能的植入物开辟了新途径。
3. Pseudocapacitance contribution in boron-doped graphite sheets for anion storage enables high-performance sodium-ion capacitors
Mater. Horiz., 2018, Advance Article
DOI: 10.1039/C8MH00156A
Intercalation pseudocapacitive materials enable very fast charging and discharging processes in batteries, which can provide both fast rate capability and high specific capacity. Currently, all the previously reported pseudocapacitive contributions in intercalation/deintercalation reactions are based on various cations （Li+, Na+, Zn2+ etc.）。 In this work, the authors demonstrate that boron-doped graphite sheets can reversibly store anions （PF6-） through both a surface-controlled pseudocapacitive reaction and a diffusion-limited intercalation/deintercalation reaction.
嵌入赝电容材料可使电池能够进行快速的充放电，提供快速倍率性能和高比容量。目前，已有报道的赝电容嵌入/脱嵌反应都是基于各种阳离子（Li+, Na+, Zn2+等）。在本工作中，作者们证明了硼掺杂石墨片可以通过表面控制的赝电容反应和扩散受限的嵌入/脱嵌反应可逆地存储阴离子（PF6-）。
Biomaterials Science （IF: 4.21）
1. Interaction of cells with patterned reactors
Biomater. Sci., 2018, 6, 793-802
DOI: 10.1039/C7BM00838D
Researchers created patterned particles through step-wise assembly with a PDMS stamp, strengthened by a final crosslinking step. Then they made the patterned particles into reactors by introducing enzyme-loaded liposomes in between polymer layers. The enzyme used was glucose oxidase, which catalyses the reaction of glucose to hydrogen peroxide. The reactor design successfully influenced the cellular response and the activity of the reactor increased with additional liposome deposition steps.
哈尔滨工业大学和丹麦奥胡斯大学的研究人员们借助PDMS印章逐步组装合成了一种图案化颗粒，并由最后的一个交联步骤进行强化。之后，他们通过在聚合物层之间引入载有酶的脂质体，将这种图案化颗粒制成了反应器。所使用的葡萄糖氧化酶能够催化由葡萄糖生成过氧化氢的反应。所设计的反应器成功地影响了细胞响应，而且其活性会随着脂质体沉积步骤的增多而增加。
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